Rapid thermal annealing of nickel-carbon nanowires for graphene nanoribbons formation

•Novel method for synthesis of graphene nanoribbons from nickel-carbon nanowires was developed.•Graphene quantum dots were used as a carbon source.•Nickel-carbon nanowires were subjected to rapid thermal annealing at different temperatures.•Graphene nanoribbons exhibit blue photoluminescence at 446n...

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Veröffentlicht in:Synthetic metals 2016-08, Vol.218, p.43-49
Hauptverfasser: Tosic, D., Markovic, Z., Jovanovic, S., Prekodravac, J., Budimir, M., Kepic, D., Holclajtner-Antunovic, I., Dramicanin, M., Todorovic-Markovic, B.
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Sprache:eng
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Zusammenfassung:•Novel method for synthesis of graphene nanoribbons from nickel-carbon nanowires was developed.•Graphene quantum dots were used as a carbon source.•Nickel-carbon nanowires were subjected to rapid thermal annealing at different temperatures.•Graphene nanoribbons exhibit blue photoluminescence at 446nm. In this paper, we present a novel method for graphene nanoribbons formation using nickel nanowires as templates. Modification of electrochemical procedure for nickel nanowires synthesis was introduced by implementing graphene quantum dots as a carbon source. Thus, nickel nanowires with graphene quantum dots were prepared. These wires were exposed to rapid thermal annealing at high temperatures (500°C, 700°C and 800°C). During this process carbon atoms dissolve in metal and precipitate to the nickel surface forming nickel-carbon nanowires. Atomic force microscopy, scanning electron microscopy and Raman spectroscopy were characterization methods used for analysis of changes in nickel-carbon nanowires properties depending on the different annealing temperatures. After etching nickel with nitric acid, graphene nanoribbons with average diameters of 32nm and average lengths of 4μm were obtained.
ISSN:0379-6779
1879-3290
DOI:10.1016/j.synthmet.2016.04.016