Oxo-rhenium catalyzed reductive coupling and deoxygenation of alcohols

Representative benzylic, allylic and α-keto alcohols are deoxygenated to alkanes and/or reductively coupled to alkane dimers by reaction with PPh 3 catalyzed by (PPh 3 ) 2 ReIO 2 ( 1 ). The newly discovered catalytic reductive coupling reaction is a rare C-C bond-forming transformation of alcohols....

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (45), p.7257-726
Hauptverfasser:	Kasner, Gabrielle R, Boucher-Jacobs, Camille, Michael McClain, J, Nicholas, Kenneth M
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols Alkanes Bonding Carbon-carbon composites Chemical reactions Coupling Deoxygenation Transformations
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Representative benzylic, allylic and α-keto alcohols are deoxygenated to alkanes and/or reductively coupled to alkane dimers by reaction with PPh 3 catalyzed by (PPh 3 ) 2 ReIO 2 ( 1 ). The newly discovered catalytic reductive coupling reaction is a rare C-C bond-forming transformation of alcohols. Representative benzylic, allylic and α-keto alcohols are deoxygenated to alkanes and/or reductively coupled to alkane dimers by reaction with PPh 3 catalyzed by (PPh 3 ) 2 ReIO 2 ( 1 ).
ISSN:	1359-7345 1364-548X
DOI:	10.1039/c6cc00537c