Preparation of K-doped TiO2 nanostructures by wet corrosion and their sunlight-driven photocatalytic performance

[Display omitted] •Potassium-doped TiO2 nanowire networks were prepared by the corrosion reaction of Ti nanoparticles in an alkaline solution.•They were applied to sunlight-driven photocatalytic degradation of differently charged dye molecules.•The adsorption of the dye molecules on the photocatalys...

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Veröffentlicht in:Applied surface science 2016-08, Vol.379, p.33-38
Hauptverfasser: Shin, Eunhye, Jin, Saera, Kim, Jiyoon, Chang, Sung-Jin, Jun, Byung-Hyuk, Park, Kwang-Won, Hong, Jongin
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Sprache:eng
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Zusammenfassung:[Display omitted] •Potassium-doped TiO2 nanowire networks were prepared by the corrosion reaction of Ti nanoparticles in an alkaline solution.•They were applied to sunlight-driven photocatalytic degradation of differently charged dye molecules.•The adsorption of the dye molecules on the photocatalyst surface is crucial for their sunlight-driven photodegradation. K-doped TiO2 nanowire networks were prepared by the corrosion reaction of Ti nanoparticles in an alkaline (potassium hydroxide: KOH) solution. The prepared nanostructures were characterized by scanning electron microscopy (SEM), Brunauer-Emmett-Teller (BET) analysis, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, X-ray diffraction (XRD) and photoluminescence (PL) spectra. Their sunlight-driven photocatalytic activity was also investigated with differently charged dye molecules, such as methylene blue, rhodamine B and methyl orange. The adsorption of the dye molecules on the photocatalyst surface would play a critical role in their selective photodegradation under sunlight illumination.
ISSN:0169-4332
1873-5584
DOI:10.1016/j.apsusc.2016.03.222