Metal-free reductive coupling of C[double bond, length as m-dash]O and C[double bond, length as m-dash]N bonds driven by visible light: use of perylene as a simple photoredox catalyst

Perylene, a simple polycyclic aromatic hydrocarbon, was used as a photoredox catalyst to enable the reductive coupling reaction of aromatic aldehydes, ketones, and an imine under visible-light irradiation using a white LED.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (76), p.11339-11342
Hauptverfasser: Okamoto, Shusuke, Kojiyama, Keita, Tsujioka, Hiroki, Sudo, Atsushi
Format: Artikel
Sprache:eng
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Zusammenfassung:Perylene, a simple polycyclic aromatic hydrocarbon, was used as a photoredox catalyst to enable the reductive coupling reaction of aromatic aldehydes, ketones, and an imine under visible-light irradiation using a white LED.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc05867a