Multiple effects of Bi doping in enhancing the thermoelectric properties of SnTe

We studied the effect of doping with Bi on the thermoelectric properties of SnTe-based materials. Doping with Bi reduced the density of holes and increased the Seebeck coefficient over a wide temperature range as a result of modulation of the carrier concentration and an increase in the density of s...

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Veröffentlicht in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2016-01, Vol.4 (34), p.13171-13175
Hauptverfasser: Zhou, Zhiwei, Yang, Junyou, Jiang, Qinghui, Luo, Yubo, Zhang, Dan, Ren, Yangyang, He, Xu, Xin, Jiwu
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container_issue 34
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container_title Journal of materials chemistry. A, Materials for energy and sustainability
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creator Zhou, Zhiwei
Yang, Junyou
Jiang, Qinghui
Luo, Yubo
Zhang, Dan
Ren, Yangyang
He, Xu
Xin, Jiwu
description We studied the effect of doping with Bi on the thermoelectric properties of SnTe-based materials. Doping with Bi reduced the density of holes and increased the Seebeck coefficient over a wide temperature range as a result of modulation of the carrier concentration and an increase in the density of states effective mass. The lattice thermal conductivity was also greatly reduced as a result of the wide frequency range of phonon scattering by multiscale architectures derived from Bi doping. A maximum ZT value of c . 1.1 at 873 K was obtained in Sn 0.94 Bi 0.06 Te, an enhancement of 165% compared with the undoped sample. We studied the effect of doping with Bi on the thermoelectric properties of SnTe-based materials.
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Density
Doping
Frequency ranges
Lattices
Modulation
Scattering
Thermal conductivity
Thermoelectricity
title Multiple effects of Bi doping in enhancing the thermoelectric properties of SnTe
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