Convective transport and scavenging of peroxides by thunderstorms observed over the central U.S. during DC3

One of the objectives of the Deep Convective Clouds and Chemistry (DC3) field experiment was to determine the scavenging of soluble trace gases by thunderstorms. We present an analysis of scavenging of hydrogen peroxide (H2O2) and methyl hydrogen peroxide (CH3OOH) from six DC3 cases that occurred in...

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Veröffentlicht in:Journal of geophysical research. Atmospheres 2016-04, Vol.121 (8), p.4272-4295
Hauptverfasser: Barth, M. C., Bela, M. M., Fried, A., Wennberg, P. O., Crounse, J. D., St. Clair, J. M., Blake, N. J., Blake, D. R., Homeyer, C. R., Brune, W. H., Zhang, L., Mao, J., Ren, X., Ryerson, T. B., Pollack, I. B., Peischl, J., Cohen, R. C., Nault, B. A., Huey, L. G., Liu, X., Cantrell, C. A.
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Sprache:eng
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Zusammenfassung:One of the objectives of the Deep Convective Clouds and Chemistry (DC3) field experiment was to determine the scavenging of soluble trace gases by thunderstorms. We present an analysis of scavenging of hydrogen peroxide (H2O2) and methyl hydrogen peroxide (CH3OOH) from six DC3 cases that occurred in Oklahoma and northeast Colorado. Estimates of H2O2 scavenging efficiencies are comparable to previous studies ranging from 79 to 97% with relative uncertainties of 5–25%. CH3OOH scavenging efficiencies ranged from 12 to 84% with relative uncertainties of 18–558%. The wide range of CH3OOH scavenging efficiencies is surprising, as previous studies suggested that CH3OOH scavenging efficiencies would be
ISSN:2169-897X
2169-8996
DOI:10.1002/2015JD024570