Structural diversity, physicochemical properties and application of imidazolium surfactants: Recent advances

The current review covers recent advances on development and investigation of cationic surfactants containing imidazolium headgroup, which are being extensively investigated for their self-aggregation properties and are currently being utilized in various conventional and non-conventional application areas. These surfactants are being used as: soft template for synthesis of mesoporous/microporous materials, drug and gene delivery agent, stabilizing agent for nanoparticles, dispersants for single/multi walled carbon nanotubes, antimicrobial and antifungal agent, viscosity modifiers, preparing nanocomposite materials, stabilizing microemulsions, corrosion inhibitors and catalyst for organic reactions. Recently several structural derivatives of these surfactants have been developed having many interesting physicochemical properties and they have demonstrated enormous potential in the area of nanotechnology, material science and biomedical science. [Display omitted] •Cationic surfactants containing positively charged imidazolium headgroup•Detailed synthetic schemes for synthesis of imidazolium surfactants•Discussion about various types of imidazolium surfactants•Self-aggregation and physicochemical properties of imidazolium surfactants•Detailed discussion about application area of imidazolium surfactants