Na ion- Conducting Ceramic as Solid Electrolyte for Rechargeable Seawater Batteries
[Display omitted] •Rechargeable seawater batteries are assembled using two Na+ conducting ceramics.•The battery with β″-Al2O3 electrolyte is irreversible even at 1 cycle.•The battery with NASICON shows a coulombic efficiency of 91% after 20 cycles.•NASICON is much more stable in seawater than β″-Al2...
Gespeichert in:
| Veröffentlicht in: | Electrochimica acta 2016-02, Vol.191, p.1-7 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 7 |
|---|---|
| container_issue | |
| container_start_page | 1 |
| container_title | Electrochimica acta |
| container_volume | 191 |
| creator | Kim, Yongil Kim, Hyojin Park, Sangmin Seo, Inseok Kim, Youngsik |
| description | [Display omitted]
•Rechargeable seawater batteries are assembled using two Na+ conducting ceramics.•The battery with β″-Al2O3 electrolyte is irreversible even at 1 cycle.•The battery with NASICON shows a coulombic efficiency of 91% after 20 cycles.•NASICON is much more stable in seawater than β″-Al2O3.
This study describes the assembly of a rechargeable seawater battery using hard carbon as the anode, seawater as the cathode, and a fast Na ion-conducting ceramic as the solid electrolyte. Two different Na ion-conducting ceramics, β″-Al2O3 and Na3Zr2Si2PO12 (NASICON), are used as the solid electrolytes in this study. The discharge capacity of the seawater battery with the NASICON solid electrolyte is 120mAhg−1 after the first cycle and over 91% coulombic efficiency after twenty cycles. However, under the same experimental conditions, the discharge capacity of the seawater battery with a β"-Al2O3 electrolyte significantly drops to 10mAhg−1 after one cycle. It is observed that the stability of NASICON in seawater is superior to that of β"-Al2O3 and impedance results of NASICON are not changed significantly compared to that of β"-Al2O3 after cycling tests. The stability of Na ion-conducting ceramics in seawater and their effects on the electrochemical performance of seawater batteries are presented and discussed. |
| doi_str_mv | 10.1016/j.electacta.2016.01.054 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1816018374</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0013468616300548</els_id><sourcerecordid>1816018374</sourcerecordid><originalsourceid>FETCH-LOGICAL-c451t-bf033c4cf13ec541abeb01504801d86a52c1ca0f9dd4978c3a1b26719a51fe2e3</originalsourceid><addsrcrecordid>eNqFkFtLw0AQhRdRsFZ_g_voS-JMNrc-1lIvUBSsPi-TzaRuSbN1N1X6702p-CoMHBjOOcN8QlwjxAiY365jbtn0NEycDIsYMIYsPREjLAsVqTKbnIoRAKoozcv8XFyEsAaAIi9gJJbPJK3rIjlzXb0zve1WcsaeNtZICnLpWlvL-eGAd-2-Z9k4L1_ZfJBfMVUtyyXTN_Xs5R31g1gOl-KsoTbw1a-Oxfv9_G32GC1eHp5m00Vk0gz7qGpAKZOaBhWbLEWquALMIC0B6zKnLDFoCJpJXaeTojSKsEryAieUYcMJq7G4OfZuvfvccej1xgbDbUsdu13QWGIOWKoiHazF0Wq8C8Fzo7febsjvNYI-YNRr_YdRHzBqQD1gHJLTY5KHT74sex2M5c5wbf3g17Wz_3b8AJ6af88</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1816018374</pqid></control><display><type>article</type><title>Na ion- Conducting Ceramic as Solid Electrolyte for Rechargeable Seawater Batteries</title><source>Elsevier ScienceDirect Journals</source><creator>Kim, Yongil ; Kim, Hyojin ; Park, Sangmin ; Seo, Inseok ; Kim, Youngsik</creator><creatorcontrib>Kim, Yongil ; Kim, Hyojin ; Park, Sangmin ; Seo, Inseok ; Kim, Youngsik</creatorcontrib><description>[Display omitted]
•Rechargeable seawater batteries are assembled using two Na+ conducting ceramics.•The battery with β″-Al2O3 electrolyte is irreversible even at 1 cycle.•The battery with NASICON shows a coulombic efficiency of 91% after 20 cycles.•NASICON is much more stable in seawater than β″-Al2O3.
This study describes the assembly of a rechargeable seawater battery using hard carbon as the anode, seawater as the cathode, and a fast Na ion-conducting ceramic as the solid electrolyte. Two different Na ion-conducting ceramics, β″-Al2O3 and Na3Zr2Si2PO12 (NASICON), are used as the solid electrolytes in this study. The discharge capacity of the seawater battery with the NASICON solid electrolyte is 120mAhg−1 after the first cycle and over 91% coulombic efficiency after twenty cycles. However, under the same experimental conditions, the discharge capacity of the seawater battery with a β"-Al2O3 electrolyte significantly drops to 10mAhg−1 after one cycle. It is observed that the stability of NASICON in seawater is superior to that of β"-Al2O3 and impedance results of NASICON are not changed significantly compared to that of β"-Al2O3 after cycling tests. The stability of Na ion-conducting ceramics in seawater and their effects on the electrochemical performance of seawater batteries are presented and discussed.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><identifier>DOI: 10.1016/j.electacta.2016.01.054</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Carbon ; Ceramics ; Discharge ; Electric batteries ; Na-ion conducting ceramic ; NASICON ; Rechargeable batteries ; Sea water ; Seawater battery ; Solid electrolytes ; Stability ; β″ - Al2O3</subject><ispartof>Electrochimica acta, 2016-02, Vol.191, p.1-7</ispartof><rights>2016 Elsevier Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c451t-bf033c4cf13ec541abeb01504801d86a52c1ca0f9dd4978c3a1b26719a51fe2e3</citedby><cites>FETCH-LOGICAL-c451t-bf033c4cf13ec541abeb01504801d86a52c1ca0f9dd4978c3a1b26719a51fe2e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0013468616300548$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27903,27904,65309</link.rule.ids></links><search><creatorcontrib>Kim, Yongil</creatorcontrib><creatorcontrib>Kim, Hyojin</creatorcontrib><creatorcontrib>Park, Sangmin</creatorcontrib><creatorcontrib>Seo, Inseok</creatorcontrib><creatorcontrib>Kim, Youngsik</creatorcontrib><title>Na ion- Conducting Ceramic as Solid Electrolyte for Rechargeable Seawater Batteries</title><title>Electrochimica acta</title><description>[Display omitted]
•Rechargeable seawater batteries are assembled using two Na+ conducting ceramics.•The battery with β″-Al2O3 electrolyte is irreversible even at 1 cycle.•The battery with NASICON shows a coulombic efficiency of 91% after 20 cycles.•NASICON is much more stable in seawater than β″-Al2O3.
This study describes the assembly of a rechargeable seawater battery using hard carbon as the anode, seawater as the cathode, and a fast Na ion-conducting ceramic as the solid electrolyte. Two different Na ion-conducting ceramics, β″-Al2O3 and Na3Zr2Si2PO12 (NASICON), are used as the solid electrolytes in this study. The discharge capacity of the seawater battery with the NASICON solid electrolyte is 120mAhg−1 after the first cycle and over 91% coulombic efficiency after twenty cycles. However, under the same experimental conditions, the discharge capacity of the seawater battery with a β"-Al2O3 electrolyte significantly drops to 10mAhg−1 after one cycle. It is observed that the stability of NASICON in seawater is superior to that of β"-Al2O3 and impedance results of NASICON are not changed significantly compared to that of β"-Al2O3 after cycling tests. The stability of Na ion-conducting ceramics in seawater and their effects on the electrochemical performance of seawater batteries are presented and discussed.</description><subject>Carbon</subject><subject>Ceramics</subject><subject>Discharge</subject><subject>Electric batteries</subject><subject>Na-ion conducting ceramic</subject><subject>NASICON</subject><subject>Rechargeable batteries</subject><subject>Sea water</subject><subject>Seawater battery</subject><subject>Solid electrolytes</subject><subject>Stability</subject><subject>β″ - Al2O3</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkFtLw0AQhRdRsFZ_g_voS-JMNrc-1lIvUBSsPi-TzaRuSbN1N1X6702p-CoMHBjOOcN8QlwjxAiY365jbtn0NEycDIsYMIYsPREjLAsVqTKbnIoRAKoozcv8XFyEsAaAIi9gJJbPJK3rIjlzXb0zve1WcsaeNtZICnLpWlvL-eGAd-2-Z9k4L1_ZfJBfMVUtyyXTN_Xs5R31g1gOl-KsoTbw1a-Oxfv9_G32GC1eHp5m00Vk0gz7qGpAKZOaBhWbLEWquALMIC0B6zKnLDFoCJpJXaeTojSKsEryAieUYcMJq7G4OfZuvfvccej1xgbDbUsdu13QWGIOWKoiHazF0Wq8C8Fzo7febsjvNYI-YNRr_YdRHzBqQD1gHJLTY5KHT74sex2M5c5wbf3g17Wz_3b8AJ6af88</recordid><startdate>20160210</startdate><enddate>20160210</enddate><creator>Kim, Yongil</creator><creator>Kim, Hyojin</creator><creator>Park, Sangmin</creator><creator>Seo, Inseok</creator><creator>Kim, Youngsik</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20160210</creationdate><title>Na ion- Conducting Ceramic as Solid Electrolyte for Rechargeable Seawater Batteries</title><author>Kim, Yongil ; Kim, Hyojin ; Park, Sangmin ; Seo, Inseok ; Kim, Youngsik</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c451t-bf033c4cf13ec541abeb01504801d86a52c1ca0f9dd4978c3a1b26719a51fe2e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Carbon</topic><topic>Ceramics</topic><topic>Discharge</topic><topic>Electric batteries</topic><topic>Na-ion conducting ceramic</topic><topic>NASICON</topic><topic>Rechargeable batteries</topic><topic>Sea water</topic><topic>Seawater battery</topic><topic>Solid electrolytes</topic><topic>Stability</topic><topic>β″ - Al2O3</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kim, Yongil</creatorcontrib><creatorcontrib>Kim, Hyojin</creatorcontrib><creatorcontrib>Park, Sangmin</creatorcontrib><creatorcontrib>Seo, Inseok</creatorcontrib><creatorcontrib>Kim, Youngsik</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kim, Yongil</au><au>Kim, Hyojin</au><au>Park, Sangmin</au><au>Seo, Inseok</au><au>Kim, Youngsik</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Na ion- Conducting Ceramic as Solid Electrolyte for Rechargeable Seawater Batteries</atitle><jtitle>Electrochimica acta</jtitle><date>2016-02-10</date><risdate>2016</risdate><volume>191</volume><spage>1</spage><epage>7</epage><pages>1-7</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><abstract>[Display omitted]
•Rechargeable seawater batteries are assembled using two Na+ conducting ceramics.•The battery with β″-Al2O3 electrolyte is irreversible even at 1 cycle.•The battery with NASICON shows a coulombic efficiency of 91% after 20 cycles.•NASICON is much more stable in seawater than β″-Al2O3.
This study describes the assembly of a rechargeable seawater battery using hard carbon as the anode, seawater as the cathode, and a fast Na ion-conducting ceramic as the solid electrolyte. Two different Na ion-conducting ceramics, β″-Al2O3 and Na3Zr2Si2PO12 (NASICON), are used as the solid electrolytes in this study. The discharge capacity of the seawater battery with the NASICON solid electrolyte is 120mAhg−1 after the first cycle and over 91% coulombic efficiency after twenty cycles. However, under the same experimental conditions, the discharge capacity of the seawater battery with a β"-Al2O3 electrolyte significantly drops to 10mAhg−1 after one cycle. It is observed that the stability of NASICON in seawater is superior to that of β"-Al2O3 and impedance results of NASICON are not changed significantly compared to that of β"-Al2O3 after cycling tests. The stability of Na ion-conducting ceramics in seawater and their effects on the electrochemical performance of seawater batteries are presented and discussed.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.electacta.2016.01.054</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0013-4686 |
| ispartof | Electrochimica acta, 2016-02, Vol.191, p.1-7 |
| issn | 0013-4686 1873-3859 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1816018374 |
| source | Elsevier ScienceDirect Journals |
| subjects | Carbon Ceramics Discharge Electric batteries Na-ion conducting ceramic NASICON Rechargeable batteries Sea water Seawater battery Solid electrolytes Stability β″ - Al2O3 |
| title | Na ion- Conducting Ceramic as Solid Electrolyte for Rechargeable Seawater Batteries |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-27T16%3A20%3A47IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Na%20ion-%20Conducting%20Ceramic%20as%20Solid%20Electrolyte%20for%20Rechargeable%20Seawater%20Batteries&rft.jtitle=Electrochimica%20acta&rft.au=Kim,%20Yongil&rft.date=2016-02-10&rft.volume=191&rft.spage=1&rft.epage=7&rft.pages=1-7&rft.issn=0013-4686&rft.eissn=1873-3859&rft_id=info:doi/10.1016/j.electacta.2016.01.054&rft_dat=%3Cproquest_cross%3E1816018374%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1816018374&rft_id=info:pmid/&rft_els_id=S0013468616300548&rfr_iscdi=true |