Synthesis, crystal growth and mechanical properties of Bismuth Silicon Oxide (BSO) single crystal

•Synthesis of Bismuth Silicon Oxide (BSO).•Single crystal growth of BSO by Czochralski (Cz) method.•Complete mechanical analysis by device fabrication point of view.•Theoretical and experimental calculations of mechanical properties. Bismuth Silicon Oxide (BSO) is an efficient material for piezo-ele...

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Veröffentlicht in:Journal of alloys and compounds 2014-03, Vol.588, p.242-247
Hauptverfasser: Riscob, B., Shkir, Mohd, Ganesh, V., Vijayan, N., Maurya, K.K., Kishan Rao, K., Bhagavannarayana, G.
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Sprache:eng
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Zusammenfassung:•Synthesis of Bismuth Silicon Oxide (BSO).•Single crystal growth of BSO by Czochralski (Cz) method.•Complete mechanical analysis by device fabrication point of view.•Theoretical and experimental calculations of mechanical properties. Bismuth Silicon Oxide (BSO) is an efficient material for piezo-electric and electro-optic applications. In this article, growth of BSO single crystal by high temperature Czochralski melt growth technique and its detailed mechanical characterization by Vickers microhardness, fracture toughness, crack propagation, brittleness index and yield strength have been reported. The raw material was synthesized by solid state reaction using the stoichiometric ratio of high purity bismuth tri-oxide and silicon di-oxide. The synthesized material was charged in the platinum crucible and then melted. The required rotation and pulling rate was optimized for BSO single crystal growth and good quality single crystal has been harvested after a time span of 5days. Powder X-ray diffraction analysis confirms the parent crystallization phase of BSO. The experimentally studied mechanical behavior of the crystal is explained using various theoretical models. The anisotropic nature of the crystals is studied using Knoop indentation technique.
ISSN:0925-8388
1873-4669
DOI:10.1016/j.jallcom.2013.11.038