Bioelectrocatalytic Oxygen Reaction and Chloride Inhibition Resistance of Laccase Immobilized on Single-walled Carbon Nanotube and Carbon Paper Electrodes

The rate of heterogeneous direct electron transfer of laccase immobilized on single-walled carbon nanotube (SWCNT) and carbon paper electrodes was evaluated by cyclic voltammetry and background-current-corrected steady-state linear voltammetry. These rates indicated that the molecular orientation of...

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Veröffentlicht in:Denki kagaku oyobi kōgyō butsuri kagaku 2016/05/05, Vol.84(5), pp.315-318
Hauptverfasser: TOMINAGA, Masato, SASAKI, Aiko, TOGAMI, Makoto
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creator TOMINAGA, Masato
SASAKI, Aiko
TOGAMI, Makoto
description The rate of heterogeneous direct electron transfer of laccase immobilized on single-walled carbon nanotube (SWCNT) and carbon paper electrodes was evaluated by cyclic voltammetry and background-current-corrected steady-state linear voltammetry. These rates indicated that the molecular orientation of laccase immobilized on the SWCNT electrode was more favorable for direct electron transfer, than that of laccase immobilized on the carbon paper electrode. The inhibition of the bioelectrocatalytic O2 reduction current of the two electrodes by chloride and fluoride were tested. The results indicated differing inhibition mechanisms by these two halides. Laccase immobilized on the SWCNT electrode exhibited high stability and high resistance to chloride inhibition.
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source J-STAGE (Japan Science & Technology Information Aggregator, Electronic) Freely Available Titles - Japanese; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals
subjects Bioelectrocatalytic
Carbon
Electrodes
Electron transfer
Inhibition
Laccase
Oxygen Reduction
Single wall carbon nanotubes
Voltammetry
title Bioelectrocatalytic Oxygen Reaction and Chloride Inhibition Resistance of Laccase Immobilized on Single-walled Carbon Nanotube and Carbon Paper Electrodes
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