Bioelectrocatalytic Oxygen Reaction and Chloride Inhibition Resistance of Laccase Immobilized on Single-walled Carbon Nanotube and Carbon Paper Electrodes
The rate of heterogeneous direct electron transfer of laccase immobilized on single-walled carbon nanotube (SWCNT) and carbon paper electrodes was evaluated by cyclic voltammetry and background-current-corrected steady-state linear voltammetry. These rates indicated that the molecular orientation of...
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Veröffentlicht in: | Denki kagaku oyobi kōgyō butsuri kagaku 2016/05/05, Vol.84(5), pp.315-318 |
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description | The rate of heterogeneous direct electron transfer of laccase immobilized on single-walled carbon nanotube (SWCNT) and carbon paper electrodes was evaluated by cyclic voltammetry and background-current-corrected steady-state linear voltammetry. These rates indicated that the molecular orientation of laccase immobilized on the SWCNT electrode was more favorable for direct electron transfer, than that of laccase immobilized on the carbon paper electrode. The inhibition of the bioelectrocatalytic O2 reduction current of the two electrodes by chloride and fluoride were tested. The results indicated differing inhibition mechanisms by these two halides. Laccase immobilized on the SWCNT electrode exhibited high stability and high resistance to chloride inhibition. |
doi_str_mv | 10.5796/electrochemistry.84.315 |
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These rates indicated that the molecular orientation of laccase immobilized on the SWCNT electrode was more favorable for direct electron transfer, than that of laccase immobilized on the carbon paper electrode. The inhibition of the bioelectrocatalytic O2 reduction current of the two electrodes by chloride and fluoride were tested. The results indicated differing inhibition mechanisms by these two halides. Laccase immobilized on the SWCNT electrode exhibited high stability and high resistance to chloride inhibition.</description><subject>Bioelectrocatalytic</subject><subject>Carbon</subject><subject>Electrodes</subject><subject>Electron transfer</subject><subject>Inhibition</subject><subject>Laccase</subject><subject>Oxygen Reduction</subject><subject>Single wall carbon nanotubes</subject><subject>Voltammetry</subject><issn>1344-3542</issn><issn>2186-2451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNptkVGPEyEUhYnRxGbd3yCJL75MhRmYgUdtqm7SuJtVnwkDl5aGQoVptP4Uf63UcX3Y-ALk5DuHm3sQeknJkg-yfwMBzJST2cHBlymfl4ItO8qfoEVLRd-0jNOnaEE7xpqOs_Y5ui5lTwihRPaylQv0651PDyF60uE8eYNvf5y3EPE9aDP5FLGOFq92IWVvAd_EnR_9H_0eSv1VRwM4ObzRxuhSgcMhjT74n2BxhT77uA3QfNchVGGl81jFTzqm6TTCHD1rd_oIGa_nYSyUF-iZ06HA9d_7Cn19v_6y-thsbj_crN5uGsMlmRpmrBWsJ5ZYzhwRZGg5tcbxlpBROGJgdE5rY7lppZSGs45wKqXjo5FMjt0Vej3nHnP6doIyqbpLAyHoCOlUFBWUSym6nlf01SN0n0451ukUHcRAWjF0F2qYKZNTKRmcOmZ_0PmsKFGX2tTj2pRgqtZWnXezc1_XuoV_Pp1rLQH-6-OXg3K1rq3W1wNqdjoriN1vftexVg</recordid><startdate>20160501</startdate><enddate>20160501</enddate><creator>TOMINAGA, Masato</creator><creator>SASAKI, Aiko</creator><creator>TOGAMI, Makoto</creator><general>The Electrochemical Society of Japan</general><general>Japan Science and Technology Agency</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QL</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope></search><sort><creationdate>20160501</creationdate><title>Bioelectrocatalytic Oxygen Reaction and Chloride Inhibition Resistance of Laccase Immobilized on Single-walled Carbon Nanotube and Carbon Paper Electrodes</title><author>TOMINAGA, Masato ; 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These rates indicated that the molecular orientation of laccase immobilized on the SWCNT electrode was more favorable for direct electron transfer, than that of laccase immobilized on the carbon paper electrode. The inhibition of the bioelectrocatalytic O2 reduction current of the two electrodes by chloride and fluoride were tested. The results indicated differing inhibition mechanisms by these two halides. Laccase immobilized on the SWCNT electrode exhibited high stability and high resistance to chloride inhibition.</abstract><cop>Tokyo</cop><pub>The Electrochemical Society of Japan</pub><doi>10.5796/electrochemistry.84.315</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Bioelectrocatalytic Carbon Electrodes Electron transfer Inhibition Laccase Oxygen Reduction Single wall carbon nanotubes Voltammetry |
title | Bioelectrocatalytic Oxygen Reaction and Chloride Inhibition Resistance of Laccase Immobilized on Single-walled Carbon Nanotube and Carbon Paper Electrodes |
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