Recent developments in free-radical-promoted C-Si formation via selective C-H/Si-H functionalization

As important and valuable alternatives to transition-metal-catalysis, free-radical strategies for C-Si bond construction via selective C-H/Si-H functionalization have been developed recently. These new reactions along with their suggested mechanisms are summarized and discussed here.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organic & biomolecular chemistry 2016-01, Vol.14 (33), p.7829-7831
Hauptverfasser: Shang, Xiaojie, Liu, Zhong-Quan
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 7831
container_issue 33
container_start_page 7829
container_title Organic & biomolecular chemistry
container_volume 14
creator Shang, Xiaojie
Liu, Zhong-Quan
description As important and valuable alternatives to transition-metal-catalysis, free-radical strategies for C-Si bond construction via selective C-H/Si-H functionalization have been developed recently. These new reactions along with their suggested mechanisms are summarized and discussed here.
doi_str_mv 10.1039/c6ob00797j
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1815699648</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1815699648</sourcerecordid><originalsourceid>FETCH-LOGICAL-c386t-9dfb7d3ceecfd6adc02a74ce56bda43e1bdcad79750b1bf2cd5e1fbc2be3bc673</originalsourceid><addsrcrecordid>eNqNkUtLAzEUhYMotlY3_gCZpQhjk0kmmSx1UKsUClbXQx43kDKPOpkp6K93-rBrV_fA-Tjcew9C1wTfE0zl1PBGYyykWJ2gMWFCxDil8vSoEzxCFyGsMCZScHaORolgmIpMjpF9BwN1F1nYQNmsq0GHyNeRawHiVllvVBmv26ZqOrBRHi995Jq2Up1v6mjjVRSgBNP5DQzmbLr08SxyfW22vir9zw68RGdOlQGuDnOCPp-fPvJZPF-8vOYP89jQjHextE4LSw2AcZYra3CiBDOQcm0Vo0C0NcoOd6ZYE-0SY1MgTptEA9WGCzpBt_vcYeGvHkJXVD4YKEtVQ9OHgmQk5VJylv0HTRgjSUYH9G6PmrYJoQVXrFtfqfa7ILjYFlDkfPG4K-BtgG8Oub2uwB7Rv4_TX7twgxA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1812441283</pqid></control><display><type>article</type><title>Recent developments in free-radical-promoted C-Si formation via selective C-H/Si-H functionalization</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Shang, Xiaojie ; Liu, Zhong-Quan</creator><creatorcontrib>Shang, Xiaojie ; Liu, Zhong-Quan</creatorcontrib><description>As important and valuable alternatives to transition-metal-catalysis, free-radical strategies for C-Si bond construction via selective C-H/Si-H functionalization have been developed recently. These new reactions along with their suggested mechanisms are summarized and discussed here.</description><identifier>ISSN: 1477-0520</identifier><identifier>EISSN: 1477-0539</identifier><identifier>DOI: 10.1039/c6ob00797j</identifier><identifier>PMID: 27403789</identifier><language>eng</language><publisher>England</publisher><ispartof>Organic &amp; biomolecular chemistry, 2016-01, Vol.14 (33), p.7829-7831</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-9dfb7d3ceecfd6adc02a74ce56bda43e1bdcad79750b1bf2cd5e1fbc2be3bc673</citedby><cites>FETCH-LOGICAL-c386t-9dfb7d3ceecfd6adc02a74ce56bda43e1bdcad79750b1bf2cd5e1fbc2be3bc673</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27403789$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Shang, Xiaojie</creatorcontrib><creatorcontrib>Liu, Zhong-Quan</creatorcontrib><title>Recent developments in free-radical-promoted C-Si formation via selective C-H/Si-H functionalization</title><title>Organic &amp; biomolecular chemistry</title><addtitle>Org Biomol Chem</addtitle><description>As important and valuable alternatives to transition-metal-catalysis, free-radical strategies for C-Si bond construction via selective C-H/Si-H functionalization have been developed recently. These new reactions along with their suggested mechanisms are summarized and discussed here.</description><issn>1477-0520</issn><issn>1477-0539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqNkUtLAzEUhYMotlY3_gCZpQhjk0kmmSx1UKsUClbXQx43kDKPOpkp6K93-rBrV_fA-Tjcew9C1wTfE0zl1PBGYyykWJ2gMWFCxDil8vSoEzxCFyGsMCZScHaORolgmIpMjpF9BwN1F1nYQNmsq0GHyNeRawHiVllvVBmv26ZqOrBRHi995Jq2Up1v6mjjVRSgBNP5DQzmbLr08SxyfW22vir9zw68RGdOlQGuDnOCPp-fPvJZPF-8vOYP89jQjHextE4LSw2AcZYra3CiBDOQcm0Vo0C0NcoOd6ZYE-0SY1MgTptEA9WGCzpBt_vcYeGvHkJXVD4YKEtVQ9OHgmQk5VJylv0HTRgjSUYH9G6PmrYJoQVXrFtfqfa7ILjYFlDkfPG4K-BtgG8Oub2uwB7Rv4_TX7twgxA</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Shang, Xiaojie</creator><creator>Liu, Zhong-Quan</creator><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7QO</scope><scope>8FD</scope><scope>FR3</scope><scope>P64</scope></search><sort><creationdate>20160101</creationdate><title>Recent developments in free-radical-promoted C-Si formation via selective C-H/Si-H functionalization</title><author>Shang, Xiaojie ; Liu, Zhong-Quan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-9dfb7d3ceecfd6adc02a74ce56bda43e1bdcad79750b1bf2cd5e1fbc2be3bc673</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shang, Xiaojie</creatorcontrib><creatorcontrib>Liu, Zhong-Quan</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Biotechnology Research Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Organic &amp; biomolecular chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shang, Xiaojie</au><au>Liu, Zhong-Quan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Recent developments in free-radical-promoted C-Si formation via selective C-H/Si-H functionalization</atitle><jtitle>Organic &amp; biomolecular chemistry</jtitle><addtitle>Org Biomol Chem</addtitle><date>2016-01-01</date><risdate>2016</risdate><volume>14</volume><issue>33</issue><spage>7829</spage><epage>7831</epage><pages>7829-7831</pages><issn>1477-0520</issn><eissn>1477-0539</eissn><abstract>As important and valuable alternatives to transition-metal-catalysis, free-radical strategies for C-Si bond construction via selective C-H/Si-H functionalization have been developed recently. These new reactions along with their suggested mechanisms are summarized and discussed here.</abstract><cop>England</cop><pmid>27403789</pmid><doi>10.1039/c6ob00797j</doi><tpages>3</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1477-0520
ispartof Organic & biomolecular chemistry, 2016-01, Vol.14 (33), p.7829-7831
issn 1477-0520
1477-0539
language eng
recordid cdi_proquest_miscellaneous_1815699648
source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
title Recent developments in free-radical-promoted C-Si formation via selective C-H/Si-H functionalization
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T11%3A43%3A25IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Recent%20developments%20in%20free-radical-promoted%20C-Si%20formation%20via%20selective%20C-H/Si-H%20functionalization&rft.jtitle=Organic%20&%20biomolecular%20chemistry&rft.au=Shang,%20Xiaojie&rft.date=2016-01-01&rft.volume=14&rft.issue=33&rft.spage=7829&rft.epage=7831&rft.pages=7829-7831&rft.issn=1477-0520&rft.eissn=1477-0539&rft_id=info:doi/10.1039/c6ob00797j&rft_dat=%3Cproquest_cross%3E1815699648%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1812441283&rft_id=info:pmid/27403789&rfr_iscdi=true