Recent developments in free-radical-promoted C-Si formation via selective C-H/Si-H functionalization
As important and valuable alternatives to transition-metal-catalysis, free-radical strategies for C-Si bond construction via selective C-H/Si-H functionalization have been developed recently. These new reactions along with their suggested mechanisms are summarized and discussed here.
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| Veröffentlicht in: | Organic & biomolecular chemistry 2016-01, Vol.14 (33), p.7829-7831 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | As important and valuable alternatives to transition-metal-catalysis, free-radical strategies for C-Si bond construction via selective C-H/Si-H functionalization have been developed recently. These new reactions along with their suggested mechanisms are summarized and discussed here. |
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| ISSN: | 1477-0520 1477-0539 |
| DOI: | 10.1039/c6ob00797j |