Asymmetric Alkylation of N‑Sulfonylbenzamides with Vinyl Ethers via C–H Bond Activation Catalyzed by Hydroxoiridium/Chiral Diene Complexes

Asymmetric Alkylation of N‑Sulfonylbenzamides with Vinyl Ethers via C–H Bond Activation Catalyzed by Hydroxoiridium/Chiral Diene Complexes

Asymmetric alkylation of N-sulfonylbenzamides with vinyl ethers via a directed C–H bond activation gave high yields of the corresponding addition products with high branch- and enantioselectivity.

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Veröffentlicht in:Journal of the American Chemical Society 2016-03, Vol.138 (12), p.4010-4013
Hauptverfasser: Hatano, Miyuki, Ebe, Yusuke, Nishimura, Takahiro, Yorimitsu, Hideki
Format: Artikel
Sprache:eng
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Zusammenfassung:Asymmetric alkylation of N-sulfonylbenzamides with vinyl ethers via a directed C–H bond activation gave high yields of the corresponding addition products with high branch- and enantioselectivity.
ISSN:0002-7863
1520-5126
DOI:10.1021/jacs.6b01591