In defense of negative temperature

This pedagogical comment highlights three misconceptions concerning the usefulness of the concept of negative temperature, being derived from the usual, often termed Boltzmann, definition of entropy. First, both the Boltzmann and Gibbs entropies must obey the same thermodynamic consistency relation....

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Veröffentlicht in:Physical review. E 2016-03, Vol.93 (3), p.032149-032149, Article 032149
1. Verfasser: Poulter, J
Format: Artikel
Sprache:eng
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Zusammenfassung:This pedagogical comment highlights three misconceptions concerning the usefulness of the concept of negative temperature, being derived from the usual, often termed Boltzmann, definition of entropy. First, both the Boltzmann and Gibbs entropies must obey the same thermodynamic consistency relation. Second, the Boltzmann entropy does obey the second law of thermodynamics. Third, there exists an integrating factor of the heat differential with both definitions of entropy.
ISSN:2470-0045
2470-0053
DOI:10.1103/PhysRevE.93.032149