A facile naphthalene-based fluorescent ‘turn-on’ chemodosimeter for palladium ions in aqueous solution

[Display omitted] A novel and simple depropargylation-triggered spontaneous cyclization reaction based fluorescent turn-on chemodosimeter for the detection of Pd2+ has been reasonably designed and developed. Based on the specific reactivity of palladium ion-promoted hydrolysis reaction, the probe ex...

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Veröffentlicht in:Tetrahedron letters 2016-03, Vol.57 (10), p.1192-1195
Hauptverfasser: Chen, Yu, Chen, Bo, Luo, Daijun, Cai, Yiyu, Wei, Yaning, Han, Yifeng
Format: Artikel
Sprache:eng
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Zusammenfassung:[Display omitted] A novel and simple depropargylation-triggered spontaneous cyclization reaction based fluorescent turn-on chemodosimeter for the detection of Pd2+ has been reasonably designed and developed. Based on the specific reactivity of palladium ion-promoted hydrolysis reaction, the probe exhibited a high selectivity and sensitivity for Pd2+ with a low detection limit (53nM, 5.7μg/L) under physiological conditions in neutral PBS (only containing 1% organic cosolvent) without any additional reagents.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2016.02.012