A prototype reversible polymersome-stabilized H sub(2)S photoejector operating under pseudophysiological conditions
Persistent self-assembled polymersome capsules are shown to solubilise and stabilize a new hydrosulfide-containing (2), as well as hydroxylated (1), malachite green derivatives in their leuco-forms in aqueous buffer solution. Photoirradiation resulted in reversible hydroxide release/hydrogen sulfide...
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Veröffentlicht in: | Organic & biomolecular chemistry 2016-07, Vol.14 (27), p.6394-6397 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | Persistent self-assembled polymersome capsules are shown to solubilise and stabilize a new hydrosulfide-containing (2), as well as hydroxylated (1), malachite green derivatives in their leuco-forms in aqueous buffer solution. Photoirradiation resulted in reversible hydroxide release/hydrogen sulfide generation. Notably, the efficient augmentation of H sub(2)S concentration to physiologically-relevant levels is shown. |
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ISSN: | 1477-0520 1477-0539 |
DOI: | 10.1039/c6ob01155a |