Development of a Sulfur-Modified Glass-Supported Pd Nanoparticle Catalyst for Suzuki–Miyaura Coupling

Development of a Sulfur-Modified Glass-Supported Pd Nanoparticle Catalyst for Suzuki–Miyaura Coupling

A safe, facile and low-leaching (up to 0.17 ppm) sulfur-modified glass-supported palladium nanoparticle catalyst has been developed for the Suzuki–Miyaura coupling of aryl halides with aryl boronic acids. Most notably, this catalyst was highly recyclable and could be used up to 10 times without any...

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Veröffentlicht in:Chemical & pharmaceutical bulletin 2016/08/01, Vol.64(8), pp.1154-1160
Hauptverfasser: Xiao, Mincen, Hoshiya, Naoyuki, Fujiki, Katsumasa, Honma, Tetsuo, Tamenori, Yusuke, Shuto, Satoshi, Fujioka, Hiromichi, Arisawa, Mitsuhiro
Format: Artikel
Sprache:eng
Schlagworte:
Boronic Acids - chemistry
Catalysis
cross-coupling
Glass - chemistry
Hydrocarbons, Halogenated - chemical synthesis
Hydrocarbons, Halogenated - chemistry
Metal Nanoparticles - chemistry
Molecular Structure
nanoparticle
palladium
Palladium - chemistry
Sulfur - chemistry
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Beschreibung
Zusammenfassung:A safe, facile and low-leaching (up to 0.17 ppm) sulfur-modified glass-supported palladium nanoparticle catalyst has been developed for the Suzuki–Miyaura coupling of aryl halides with aryl boronic acids. Most notably, this catalyst was highly recyclable and could be used up to 10 times without any discernible decrease in its activity.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.c16-00261