Reversible transformation of self-assemblies and fluorescence by protonation-deprotonation in pyrimidinylene-phenylene macrocycles

Reversible transformation of self-assemblies and fluorescence by protonation-deprotonation in pyrimidinylene-phenylene macrocycles

We describe herein that the self-assembled nanoobjects based on pyrimidinylene-phenylene macrocycles, 1 and 2, which possess the capability to respond to acid-stimuli by proton binding, can undergo reversible transformation of self-assemblies and fluorescence switching by protonation-deprotonation.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-03, Vol.52 (23), p.4357-4360
Hauptverfasser: Xiao, Duoduo, Zhang, Siqi, Zhang, Dengqing, Xie, Dahai, Zeng, Qingdao, Xiang, Yunjie, Ning, Ruguang, Li, Xianying, Jin, Wusong
Format: Artikel
Sprache:eng
Schlagworte:
Binding
Fluorescence
Macrocyclic compounds
Nanostructure
Self assembly
Switching
Transformations
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Zusammenfassung:We describe herein that the self-assembled nanoobjects based on pyrimidinylene-phenylene macrocycles, 1 and 2, which possess the capability to respond to acid-stimuli by proton binding, can undergo reversible transformation of self-assemblies and fluorescence switching by protonation-deprotonation.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc00943c