Cooperative catalysis for the direct hydrodeoxygenation of vegetable oils into diesel-range alkanes over Pd/NbOPO sub(4)

Cooperative catalysis for the direct hydrodeoxygenation of vegetable oils into diesel-range alkanes over Pd/NbOPO sub(4)

Near quantitative carbon yields of diesel-range alkanes were achieved from the hydrodeoxygenation of triglycerides over Pd/NbOPO sub(4) under mild conditions with no catalyst deactivation: catalyst characterization and theoretical calculations suggest that the high hydrodeoxygenation activity origin...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-03, Vol.52 (29), p.5160-5163
Hauptverfasser: Xia, Qineng, Zhuang, Xiaojing, Li, Molly Meng-Jung, Peng, Yung-Kang, Liu, Guoliang, Wu, Tai-Sing, Soo, Yun-Liang, Gong, Xue-Qing, Wang, Yanqin, Tsang, Shik Chi Edman
Format: Artikel
Sprache:eng
Schlagworte:
Alkanes
Carbon
Catalysts
Deactivation
Mathematical analysis
Palladium
Synergistic effect
Vegetable oils
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Zusammenfassung:Near quantitative carbon yields of diesel-range alkanes were achieved from the hydrodeoxygenation of triglycerides over Pd/NbOPO sub(4) under mild conditions with no catalyst deactivation: catalyst characterization and theoretical calculations suggest that the high hydrodeoxygenation activity originated from the synergistic effect of Pd and strong Lewis acidity on the unique structure of NbOPO sub(4).
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc10419j