Dielectric investigations of nanocomposites based on Matrimid and polyhedral oligomeric phenethyl-silsesquioxanes (POSS)

Matrimid and Matrimid/PhenethylPOSS nanocomposites films were prepared by solution casting. They can be considered as potential membrane materials for gas separation. Their dielectric properties were investigated using Broadband Dielectric Spectroscopy (BDS) in combination with standard techniques. Matrimid shows one relaxation process assigned as β*-relaxation and a conductivity contribution. The relaxation process has a high activation energy of 99 kJ/mol. Thus this process is supposed to be of cooperative nature due to a π–π stacking of the phenyl rings of Matrimid. The influence of the thermal history on Matrimid was analyzed with BDS as well where an annealing effect is found. The Matrimid nanocomposites show up to a concentration of about 4 wt% PhenethylPOSS a miscibility on a molecular level. For higher concentrations a phase separated structure was indicated. The conductivity of both systems is explained by π–π stacking of the phenyl rings which enhances charge transport. [Display omitted] •The relaxation and conductivity phenomena for Matrimid are discussed in detail.•The high activation energy of this β*-relaxation is attributed to agglomerates.•Nanocomposites of Matrimid and PhenethylPOSS are prepared.•A phase separation for Matrimid/POSS composites is proofed by a MWS polarization.