Fully-substituted 1,3-Butadienes as π-Conjugated Linkers between Pyrenes

Pyrenyl-substituted 1,3-butadienes bearing alkyl and aryl groups have been synthesized by palladium-catalyzed addition of 2-borylpyrene to internal alkynes. On UV irradiation, 1-pyrenylbutadienes undergo photochromism in solution. In the solid state, 1-pyrenyl-1,2,3,4-tetraaryl-1,3-butadiene exhibit...

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Veröffentlicht in:Chemistry letters 2016-04, Vol.45 (4), p.403-405
Hauptverfasser: Oda, Kazuma, Hiroto, Satoru, Sakamaki, Daisuke, Seki, Shu, Shinokubo, Hiroshi
Format: Artikel
Sprache:eng
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Zusammenfassung:Pyrenyl-substituted 1,3-butadienes bearing alkyl and aryl groups have been synthesized by palladium-catalyzed addition of 2-borylpyrene to internal alkynes. On UV irradiation, 1-pyrenylbutadienes undergo photochromism in solution. In the solid state, 1-pyrenyl-1,2,3,4-tetraaryl-1,3-butadiene exhibits red-shifted and broad emission as compared with the alkylated butadiene. The charge-carrier mobility of 1-pyrenyl-1,2,3,4-tetraalkyl-1,3-butadiene is higher than that of the arylated butadiene.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.151181