Light-Modulated Intermittent Wave Groups in a Diffusively Fed Reactive Gel
Inspired by the biological growth that takes place in time‐varying external fields such as light or temperature, we design an open reaction‐diffusion system in order to investigate growth dynamics. The system is composed of the Belousov–Zhabotinsky (BZ) oscillatory reaction coupled with a copolymer...
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Veröffentlicht in: | Angewandte Chemie 2016-04, Vol.128 (16), p.5072-5075 |
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Sprache: | eng |
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Zusammenfassung: | Inspired by the biological growth that takes place in time‐varying external fields such as light or temperature, we design an open reaction‐diffusion system in order to investigate growth dynamics. The system is composed of the Belousov–Zhabotinsky (BZ) oscillatory reaction coupled with a copolymer gel consisting of NIPAAm and a photosensitive ruthenium catalyst. When subject to a unidirectional flow of the BZ reactants, the system displays groups of chemical waves whose structure depends upon the period and amplitude of illumination. Simulations of a modified six‐variable Oregonator model exhibit all the complex wave groups found in our experiments. Studying this growth structure may aid in understanding the influence of periodic environmental variation on complex growth processes in living systems.
Ein Copolymergel aus einem Ruthenium‐Katalysator und NIPAAM wurde mit Belousov‐Zhabotinsky‐Reagentien zu einem Reaktionssystem mit diffusivem Eintrag gekoppelt. Periodische Perturbation durch eine äußere Lichtquelle induziert Wellengruppen, die an das Entwicklungsmuster von fiederschnittigen Blättern erinnnern. |
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ISSN: | 0044-8249 1521-3757 |
DOI: | 10.1002/ange.201600889 |