Preparation and characterization of nanocomposite PVDF ultrafiltration membrane embedded with nanoporous SAPO-34 to improve permeability and antifouling performance

[Display omitted] •PVDF ultrafiltration membrane blended with SAPO-34 zeolite was prepared.•The membranes were prepared by the non-solvent induced phase inversion method.•The SAPO-34 filled PVDF membranes show higher hydrophilicity and water flux.•SAPO-34 has no obvious influence on the membrane cro...

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Veröffentlicht in:Separation and purification technology 2016-05, Vol.163, p.300-309
Hauptverfasser: Vatanpour, Vahid, Yekavalangi, Mohammad Ehsan, Safarpour, Mahdie
Format: Artikel
Sprache:eng
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Zusammenfassung:[Display omitted] •PVDF ultrafiltration membrane blended with SAPO-34 zeolite was prepared.•The membranes were prepared by the non-solvent induced phase inversion method.•The SAPO-34 filled PVDF membranes show higher hydrophilicity and water flux.•SAPO-34 has no obvious influence on the membrane cross-sectional structure.•Membrane with 0.5wt% SAPO-34 show the best antifouling performance (FRR=89.4%). A novel polyvinylidene fluoride (PVDF) ultrafiltration membrane blended with different concentrations of SAPO-34 nanoporous zeolite was fabricated by the non-solvent induced phase inversion method. The prepared blended membranes were characterized by scanning electron microscopy (SEM), water contact angle, porosity, energy dispersive X-ray (EDX), and permeation analyses as well as fouling and rejection tests. The SEM images of the membranes showed an asymmetric structure possessing a dense top-layer and a combination of spongy and finger-like porous sub-layer. The modified PVDF membranes had lower water contact angle, higher hydrophilicity and water flux due to the presence of hydrophilic SAPO-34 zeolite in the polymer medium. All of the nanocomposite membranes showed higher flux recovery ratio (FRR (%)) compared to the unfilled PVDF membrane. The membrane containing 0.5wt% SAPO-34 had the best antifouling performance (FRR=89.4%) with a bovine serum albumin (BSA) rejection value more than 99%.
ISSN:1383-5866
1873-3794
DOI:10.1016/j.seppur.2016.03.011