Conductive Nanostructured Scaffolds Render Low Local Current Density to Inhibit Lithium Dendrite Growth

A nanostructured lithium‐metal anode employing an unstacked graphene “drum” and dual‐salt electrolyte brings about a dendrite‐free lithium depositing morphology. On the one hand, the unstacked graphene framework with ultrahigh specific surface area guarantees an ultralow local current density that p...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Weinheim) 2016-03, Vol.28 (11), p.2155-2162
Hauptverfasser: Zhang, Rui, Cheng, Xin-Bing, Zhao, Chen-Zi, Peng, Hong-Jie, Shi, Jia-Le, Huang, Jia-Qi, Wang, Jinfu, Wei, Fei, Zhang, Qiang
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A nanostructured lithium‐metal anode employing an unstacked graphene “drum” and dual‐salt electrolyte brings about a dendrite‐free lithium depositing morphology. On the one hand, the unstacked graphene framework with ultrahigh specific surface area guarantees an ultralow local current density that prevents the growth of lithium dendrites. On the other hand, the stable, flexible, and compact solid electrolyte interphase layer induced by the dual‐salt electrolyte protects the deposited lithium layers.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.201504117