Heterometallic Na sub(6)Co sub(3) Phenylsilsesquioxane Exhibiting Slow Dynamic Behavior in its Magnetization

Heterometallic Na sub(6)Co sub(3) Phenylsilsesquioxane Exhibiting Slow Dynamic Behavior in its Magnetization

A heterometallic phenylsilsesquioxane [(PhSiO sub(1,5)) sub(22)(CoO) sub(3)(NaO sub(0.5)) sub(6)](EtOH) sub(6)(H sub(2) O) 1 cage architecture of Co super(II) ions in a triangular topology exhibits a slow dynamic behavior in its magnetization, induced by the freezing of the spins of individual molec...

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Veröffentlicht in:Chemistry : a European journal 2015-12, Vol.21 (51), p.18563-18565
Hauptverfasser: Bilyachenko, Alexey N, Yalymov, Alexey I, Korlyukov, Alexander A, Long, Jerome, Larionova, Joulia, Guari, Yannick, Zubavichus, Yan V, Trigub, Alexander L, Shubina, Elena S, Eremenko, Igor L, Efimov, Nikolay N, Levitsky, Mikhail M
Format: Artikel
Sprache:eng
Schlagworte:
Architecture
Cage
Dynamics
Freezing
Magnetization
Topology
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Zusammenfassung:A heterometallic phenylsilsesquioxane [(PhSiO sub(1,5)) sub(22)(CoO) sub(3)(NaO sub(0.5)) sub(6)](EtOH) sub(6)(H sub(2) O) 1 cage architecture of Co super(II) ions in a triangular topology exhibits a slow dynamic behavior in its magnetization, induced by the freezing of the spins of individual molecules. A cobalt(II) phenylsilsesquioxane [(PhSiO sub(1,5)) sub(22)(CoO) sub(3)(NaO sub(0.5)) sub(6)](EtOH) sub(6)(H sub(2) O) in a triangular topology exhibits a slow dynamic behavior in its magnetization, induced by the freezing of the spins of individual molecules.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201503635