Efficient Total Synthesis of Marine Alkaloid (-)-NakadomarinA
Z's top: For the total synthesis of the marine alkaloid (-)-nakadomarinA, (-)-camphorsulfonic acid assisted, Z-selective, olefin RCM of a monoamine (less polar) rather than a diamine (more polar) was found to be highly practical for constructing the Fring. The ABCD-tetracyclic core was assemble...
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| Veröffentlicht in: | Chemistry : a European journal 2011-11, Vol.17 (45), p.12569-12572 |
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| container_end_page | 12572 |
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| container_issue | 45 |
| container_start_page | 12569 |
| container_title | Chemistry : a European journal |
| container_volume | 17 |
| creator | Cheng, Bin Wu, Fufang Yang, Xiaobao Zhou, Yuedong Wan, Xiaolong Zhai, Hongbin |
| description | Z's top: For the total synthesis of the marine alkaloid (-)-nakadomarinA, (-)-camphorsulfonic acid assisted, Z-selective, olefin RCM of a monoamine (less polar) rather than a diamine (more polar) was found to be highly practical for constructing the Fring. The ABCD-tetracyclic core was assembled through a novel efficacious PtCl sub(2)-promoted cascade reaction sequence (see scheme). |
| doi_str_mv | 10.1002/chem.201102101 |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 0947-6539 |
| ispartof | Chemistry : a European journal, 2011-11, Vol.17 (45), p.12569-12572 |
| issn | 0947-6539 1521-3765 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1800495058 |
| source | Wiley Online Library - AutoHoldings Journals |
| subjects | Alkaloids Chemistry Construction Diamines Effectiveness Marine Olefins RCM Synthesis |
| title | Efficient Total Synthesis of Marine Alkaloid (-)-NakadomarinA |
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