$Structure and Bonding Nature of the Strained Lewis Acid 3-Methyl-1-boraadamantane: A Case Study Employing a New Data-Analysis Procedure in Gas Electron Diffraction$

Structure and Bonding Nature of the Strained Lewis Acid 3-Methyl-1-boraadamantane: A Case Study Employing a New Data-Analysis Procedure in Gas Electron Diffraction

Base‐free 3‐methyl‐1‐boraadamantane was synthesized by starting from its known THF adduct, transforming it to a butylate‐complex with n‐butyllithium, cleaving the cage with acetyl chloride to give 3‐n‐butyl‐5‐methyl‐7‐methylene‐3‐borabicyclo[3.3.1]nonane and closing the cage again by reacting the la...

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Veröffentlicht in:	Chemistry : a European journal 2012-08, Vol.18 (34), p.10585-10594
Hauptverfasser:	Vishnevskiy, Yury V., Abaev, Maxim A., Rykov, Anatolii N., Gurskii, Mikhail E., Belyakov, Pavel A., Erdyakov, Sergey Yu, Bubnov, Yuri N., Mitzel, Norbert W.
Format:	Artikel
Sprache:	eng
Schlagworte:	Bonding boraadamantane boron Cage Chemical bonds Chemistry Diffraction Electron diffraction Elongation gas-phase electron diffraction Lewis acids Mathematical models NBO Orbitals Regularization
Online-Zugang:	Volltext
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