[Cu(dap)2Cl] As an Efficient Visible-Light-Driven Photoredox Catalyst in Carbon-Carbon Bond-Forming Reactions

[Cu(dap)2Cl] As an Efficient Visible-Light-Driven Photoredox Catalyst in Carbon-Carbon Bond-Forming Reactions

Copper sees the light of day: [Cu(dap)2Cl] proved to be an excellent photoredox catalyst for atom‐transfer radical addition reactions, as well as for allylation reactions (see scheme), providing an attractive alternative to commonly used iridium‐ and ruthenium‐based catalysts.

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Veröffentlicht in:Chemistry : a European journal 2012-06, Vol.18 (24), p.7336-7340
Hauptverfasser: Pirtsch, Michael, Paria, Suva, Matsuno, Taisuke, Isobe, Hiroyuki, Reiser, Oliver
Format: Artikel
Sprache:eng
Schlagworte:
Allyl compounds
allylation
atom-transfer radical addition
Bonding
Carbon
Carbon-carbon composites
Catalysts
Chemical reactions
Chemistry
Copper
Iridium
photochemistry
Photoredox catalysis
Radicals
redox chemistry
Ruthenium
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Zusammenfassung:Copper sees the light of day: [Cu(dap)2Cl] proved to be an excellent photoredox catalyst for atom‐transfer radical addition reactions, as well as for allylation reactions (see scheme), providing an attractive alternative to commonly used iridium‐ and ruthenium‐based catalysts.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201200967