Eutectic Syntheses of Graphitic Carbon with High Pyrazinic Nitrogen Content

Mixtures of phenols/ketones and urea show eutectic behavior upon gentle heating. These mixtures possess liquid‐crystalline‐like phases that can be processed. The architecture of phenol/ketone acts as structure‐donating motif, while urea serves as melting‐point reduction agent. Condensation at elevat...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Weinheim) 2016-02, Vol.28 (6), p.1287-1294
Hauptverfasser: Fechler, Nina, Zussblatt, Niels P., Rothe, Regina, Schlögl, Robert, Willinger, Marc-Georg, Chmelka, Bradley F., Antonietti, Markus
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Mixtures of phenols/ketones and urea show eutectic behavior upon gentle heating. These mixtures possess liquid‐crystalline‐like phases that can be processed. The architecture of phenol/ketone acts as structure‐donating motif, while urea serves as melting‐point reduction agent. Condensation at elevated temperatures results in nitrogen‐containing carbons with remarkably high nitrogen content of mainly pyrazinic nature.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.201501503