The ruthenium-catalysed selective synthesis of mono-deuterated terminal alkynes

The ruthenium-catalysed selective synthesis of mono-deuterated terminal alkynes

We report an efficient catalytic method for the synthesis of mono-deuterated terminal alkynes directly from deuterium oxide, catalysed by a Ru(II) pincer complex in which the reaction proceeds via Ru-acetylide intermediates and amine-amide metal-ligand cooperation.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (24), p.4509-4512
Hauptverfasser: Chatterjee, Basujit, Gunanathan, Chidambaram
Format: Artikel
Sprache:eng
Schlagworte:
Alkynes
Catalysis
Catalysts
Cooperation
Heavy water
Synthesis
Synthesis (chemistry)
Terminals
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Zusammenfassung:We report an efficient catalytic method for the synthesis of mono-deuterated terminal alkynes directly from deuterium oxide, catalysed by a Ru(II) pincer complex in which the reaction proceeds via Ru-acetylide intermediates and amine-amide metal-ligand cooperation.
ISSN:1359-7345
1364-548X
DOI:10.1039/c6cc01401a