Site-specific synthesis of a hybrid boron-graphene salt

Site-specific synthesis of a hybrid boron-graphene salt

We report the first example of an ionic graphene salt containing boron. An anionic charge is introduced to the graphene surface by means of 7,8-nido-[C2B9H11](-) carborane clusters covalently and electronically bound to the graphene lattice, and this new material was isolated as its Cs(+) salt.

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2016-01, Vol.52 (6), p.1290-1292
Hauptverfasser: Kahlert, Jan U, Austin, Christopher J D, Hall, Andrew J, Rawal, Aditya, Hook, James M, Rendina, Louis M, Choucair, Mohammad
Format: Artikel
Sprache:eng
Schlagworte:
Boron
Carborane
Charge
Clusters
Covalence
Graphene
Lattices
Synthesis
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Zusammenfassung:We report the first example of an ionic graphene salt containing boron. An anionic charge is introduced to the graphene surface by means of 7,8-nido-[C2B9H11](-) carborane clusters covalently and electronically bound to the graphene lattice, and this new material was isolated as its Cs(+) salt.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc07611k