Cyclic Silanols with Long Alkyl Chains

Facile synthesis of cyclotrisiloxanetriols ((RSi(OH)O)3; R = hexyl and octyl) bearing a relatively unusual six-membered siloxane ring was accomplished by taking advantage of long alkyl chains. The synthetic method, details of the reaction pathway, and hydrogen-bonded crystal structure of the product...

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Veröffentlicht in:Chemistry letters 2016-03, Vol.45 (3), p.309-311
Hauptverfasser: Murakami, Shinji, Egawa, Yasunobu, Kuramochi, Chika, Takeda, Nobuhiro, Unno, Masafumi
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container_title Chemistry letters
container_volume 45
creator Murakami, Shinji
Egawa, Yasunobu
Kuramochi, Chika
Takeda, Nobuhiro
Unno, Masafumi
description Facile synthesis of cyclotrisiloxanetriols ((RSi(OH)O)3; R = hexyl and octyl) bearing a relatively unusual six-membered siloxane ring was accomplished by taking advantage of long alkyl chains. The synthetic method, details of the reaction pathway, and hydrogen-bonded crystal structure of the product are described.
doi_str_mv 10.1246/cl.151143
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source Oxford University Press Journals All Titles (1996-Current)
subjects Bearing
Crystal structure
Hydrogen bonding
Pathways
Siloxanes
Synthesis
title Cyclic Silanols with Long Alkyl Chains
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