Cyclic Silanols with Long Alkyl Chains

Cyclic Silanols with Long Alkyl Chains

Facile synthesis of cyclotrisiloxanetriols ((RSi(OH)O)3; R = hexyl and octyl) bearing a relatively unusual six-membered siloxane ring was accomplished by taking advantage of long alkyl chains. The synthetic method, details of the reaction pathway, and hydrogen-bonded crystal structure of the product...

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Veröffentlicht in:Chemistry letters 2016-03, Vol.45 (3), p.309-311
Hauptverfasser: Murakami, Shinji, Egawa, Yasunobu, Kuramochi, Chika, Takeda, Nobuhiro, Unno, Masafumi
Format: Artikel
Sprache:eng
Schlagworte:
Bearing
Crystal structure
Hydrogen bonding
Pathways
Siloxanes
Synthesis
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Beschreibung
Zusammenfassung:Facile synthesis of cyclotrisiloxanetriols ((RSi(OH)O)3; R = hexyl and octyl) bearing a relatively unusual six-membered siloxane ring was accomplished by taking advantage of long alkyl chains. The synthetic method, details of the reaction pathway, and hydrogen-bonded crystal structure of the product are described.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.151143