Direct oxidative amidation between methylarenes and amines in water

Direct oxidative amidation between methylarenes and amines in water

An environmentally friendly direct oxidative amidation between methylarenes and free amines was developed. The aromatic amide could be prepared efficiently from raw chemicals by employing TBHP as a "green" oxidant with co-catalysis of TBAI and FeCl sub(3) in water.

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2015-05, Vol.17 (5), p.2741-2744
Hauptverfasser: Wang, Tao, Yuan, Lin, Zhao, Zhenguang, Shao, Ailong, Gao, Meng, Huang, Yangfei, Xiong, Fei, Zhang, Huali, Zhao, Junfeng
Format: Artikel
Sprache:eng
Schlagworte:
Amides
Amines
Oxidants
Oxidizing agents
Raw
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Beschreibung
Zusammenfassung:An environmentally friendly direct oxidative amidation between methylarenes and free amines was developed. The aromatic amide could be prepared efficiently from raw chemicals by employing TBHP as a "green" oxidant with co-catalysis of TBAI and FeCl sub(3) in water.
ISSN:1463-9262
1463-9270
DOI:10.1039/c5gc00299k