Formation of Acyl and Dioxycarbene Ruthenium Complexes via Double C–S Bond Cleavage and CO Insertion

Ruthenium complexes containing an N,N,C,S-metalloligand or an N,N,C,O-organoligand with a sulfido carbonyl Ru cluster were obtained by the reaction of 6-(4′′-dibenzothienyl)-2,2′-bipyridine with [Ru3(CO)12]. The dibenzothienyl group undergoes double carbon–sulfur bond cleavage and CO insertion react...

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Veröffentlicht in:	Bulletin of the Chemical Society of Japan 2015-04, Vol.88 (4), p.613-615
Hauptverfasser:	Santo, Kiyokazu, Hirotsu, Masakazu, Kawamoto, Keisuke, Nishioka, Takanori, Kinoshita, Isamu
Format:	Artikel
Sprache:	eng
Schlagworte:	Bonding Bridging Carbonyls Cleavage Clusters Formations Insertion Ruthenium
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creator	Santo, Kiyokazu Hirotsu, Masakazu Kawamoto, Keisuke Nishioka, Takanori Kinoshita, Isamu
description	Ruthenium complexes containing an N,N,C,S-metalloligand or an N,N,C,O-organoligand with a sulfido carbonyl Ru cluster were obtained by the reaction of 6-(4′′-dibenzothienyl)-2,2′-bipyridine with [Ru3(CO)12]. The dibenzothienyl group undergoes double carbon–sulfur bond cleavage and CO insertion reactions to give a bridging acyl group and a metallacyclic dioxycarbene donor.
doi_str_mv	10.1246/bcsj.20140379
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source	Oxford University Press Journals All Titles (1996-Current)
subjects	Bonding Bridging Carbonyls Cleavage Clusters Formations Insertion Ruthenium
title	Formation of Acyl and Dioxycarbene Ruthenium Complexes via Double C–S Bond Cleavage and CO Insertion
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