Formation of Acyl and Dioxycarbene Ruthenium Complexes via Double C–S Bond Cleavage and CO Insertion

Formation of Acyl and Dioxycarbene Ruthenium Complexes via Double C–S Bond Cleavage and CO Insertion

Ruthenium complexes containing an N,N,C,S-metalloligand or an N,N,C,O-organoligand with a sulfido carbonyl Ru cluster were obtained by the reaction of 6-(4′′-dibenzothienyl)-2,2′-bipyridine with [Ru3(CO)12]. The dibenzothienyl group undergoes double carbon–sulfur bond cleavage and CO insertion react...

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Veröffentlicht in:Bulletin of the Chemical Society of Japan 2015-04, Vol.88 (4), p.613-615
Hauptverfasser: Santo, Kiyokazu, Hirotsu, Masakazu, Kawamoto, Keisuke, Nishioka, Takanori, Kinoshita, Isamu
Format: Artikel
Sprache:eng
Schlagworte:
Bonding
Bridging
Carbonyls
Cleavage
Clusters
Formations
Insertion
Ruthenium
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Zusammenfassung:Ruthenium complexes containing an N,N,C,S-metalloligand or an N,N,C,O-organoligand with a sulfido carbonyl Ru cluster were obtained by the reaction of 6-(4′′-dibenzothienyl)-2,2′-bipyridine with [Ru3(CO)12]. The dibenzothienyl group undergoes double carbon–sulfur bond cleavage and CO insertion reactions to give a bridging acyl group and a metallacyclic dioxycarbene donor.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.20140379