Tunable thermomorphism and applications of ionic liquid analogues of Girard's reagents

Tunable thermomorphism and applications of ionic liquid analogues of Girard's reagents

A series of ionic liquids based on Girard's reagents was synthesised. Their tunable thermomorphic behaviour with water was demonstrated, and slight modifications in the cationic structure led to drastic changes in their water miscibility. Their phase behaviour, involving monophasic-biphasic tra...

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2014, Vol.16 (9), p.4115-4121
Hauptverfasser: Blesic, Marijana, Gunaratne, HQNimal, Jacquemin, Johan, Nockemann, Peter, Olejarz, Sonia, Seddon, Kenneth R, Strauss, Christopher R
Format: Artikel
Sprache:eng
Schlagworte:
Cationic
Dyes
Extraction
Ionic liquids
Miscibility
Phase transformations
Reagents
Scavenging
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Zusammenfassung:A series of ionic liquids based on Girard's reagents was synthesised. Their tunable thermomorphic behaviour with water was demonstrated, and slight modifications in the cationic structure led to drastic changes in their water miscibility. Their phase behaviour, involving monophasic-biphasic transitions, drove a number of practical applications, including scavenging water-soluble dyes and the extraction of metals from water.
ISSN:1463-9262
1463-9270
DOI:10.1039/c4gc01159g