Antimony/Graphitic Carbon Composite Anode for High-Performance Sodium-Ion Batteries

Although the room-temperature rechargeable sodium-ion battery has emerged as an attractive alternative energy storage solution for large-scale deployment, major challenges toward practical sodium-ion battery technology remain including identification and engineering of anode materials that are both...

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Veröffentlicht in:ACS applied materials & interfaces 2016-06, Vol.8 (22), p.13871-13878
Hauptverfasser: Zhao, Xin, Vail, Sean A, Lu, Yuhao, Song, Jie, Pan, Wei, Evans, David R, Lee, Jong-Jan
Format: Artikel
Sprache:eng
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Zusammenfassung:Although the room-temperature rechargeable sodium-ion battery has emerged as an attractive alternative energy storage solution for large-scale deployment, major challenges toward practical sodium-ion battery technology remain including identification and engineering of anode materials that are both technologically feasible and economical. Herein, an antimony-based anode is developed by incorporating antimony into graphitic carbon matrices using low-cost materials and scalable processes. The composite anode exhibits excellent overall performance in terms of packing density, fast charge/discharge capability and cyclability, which is enabled by the conductive and compact graphitic network. A full cell design featuring this composite anode with a hexacyanometallate cathode achieves superior power output and low polarization, which offers the potential for realizing a high-performance, cost-effective sodium-ion battery.
ISSN:1944-8244
1944-8252
DOI:10.1021/acsami.6b01761