Hydrophilicity improvement of mercerized bacterial cellulose films by polyethylene glycol graft

⿢Mercerized bacterial nanocellulose (BNCm) was grafted to polyethylene glycol with different molar ratios (BNCm-PEGs).⿢Crystallinity of BNCm was preserved after grafting with PEGs.⿢Grafting of PEG was observed on C-2, C-3 and C-6 of BNCm mainly on amorphous zones.⿢Nanofilms produced with BNCm-PEG sh...

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Veröffentlicht in:International journal of biological macromolecules 2016-05, Vol.86, p.599-605
Hauptverfasser: Silva, Renata da, Sierakowski, Maria R., Bassani, Helen P., Zawadzki, Sônia F., Pirich, Cleverton L., Ono, Lucy, de Freitas, Rilton A.
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Sprache:eng
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Zusammenfassung:⿢Mercerized bacterial nanocellulose (BNCm) was grafted to polyethylene glycol with different molar ratios (BNCm-PEGs).⿢Crystallinity of BNCm was preserved after grafting with PEGs.⿢Grafting of PEG was observed on C-2, C-3 and C-6 of BNCm mainly on amorphous zones.⿢Nanofilms produced with BNCm-PEG showed an increased free energy of surface comparatively to BNCm.⿢All BNCm-PEG films retained the biocompatibility of BNCm films. In this work, polyethylene glycol (PEG), of tree distinct molar masses (200, 300 and 400gmol⿿1), was grafted onto mercerized bacterial nanocellulose (BNCm) and applied to produce nanofilms (BNCm-PEG). The products BNCm-PEG were characterized by NMR and thermal analysis. Solid-state NMR and X-ray diffraction analyses exhibited no significant differences in index of BNCm-PEG derivatives compared to BNCm, indicating that grafting reaction did not modify the BNCm crystalline structure. The apparent contact angle of the films showed that BNCm-PEG films exhibited a pronounced increase in the polar components (BNCm: 8.1mNm⿿1 vs BNCm-PEG400: 29.4mNm⿿1), and a decrease in dispersive components (BNCm: 41.7mNm⿿1 vs BNCm-PEG400: 35.2mNm⿿1) of the surface free energy. The BNCm-PEG films were more hydrophilic than BNCm and retained the biocompatibility with L929 fibroblast cells culture.
ISSN:0141-8130
1879-0003
DOI:10.1016/j.ijbiomac.2016.01.115