Selective Dynamic Assembly of Disulfide Macrocyclic Helical Foldamers with Remote Communication of Handedness

Disulfide bridge formation was investigated in helical aromatic oligoamide foldamers. Depending on the position of thiol‐bearing side chains, exclusive intramolecular or intermolecular disulfide bridging may occur. The two processes are capable of self‐sorting, presumably by dynamic exchange. Quanti...

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Veröffentlicht in:	Angewandte Chemie International Edition 2016-06, Vol.55 (24), p.6848-6852
Hauptverfasser:	Tsiamantas, Christos, de Hatten, Xavier, Douat, Céline, Kauffmann, Brice, Maurizot, Victor, Ihara, Hirotaka, Takafuji, Makoto, Metzler-Nolte, Nils, Huc, Ivan
Format:	Artikel
Sprache:	eng
Schlagworte:	chirality Crystal structure foldamers Handedness macrocycles remote conformational communication thiol-disulfide exchange
Online-Zugang:	Volltext
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