Role of substrate and annealing temperature on the structure of ZnO and Al sub(x)Zn sub(1-x)O thin films for solar cell applications
This paper reports on the deposition of pure and 5 at% Al doped ZnO (AZO) prepared by sol-gel and applied to the substrates by spin-coating, and the role of annealing temperature on the crystallinity of these layers. It is found that both ZnO and AZO are largely amorphous when coated on glass compar...
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Veröffentlicht in: | Physica. B, Condensed matter Condensed matter, 2016-01, Vol.480, p.72-79 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | This paper reports on the deposition of pure and 5 at% Al doped ZnO (AZO) prepared by sol-gel and applied to the substrates by spin-coating, and the role of annealing temperature on the crystallinity of these layers. It is found that both ZnO and AZO are largely amorphous when coated on glass compared to n-Si(lll), as substrates. On both substrates, X-ray diffraction (XRD) shows that the crystallinity improves as annealing temperature is raised from 200 to 600 [degrees]C with better crystallinity on Si substrates. The thickness of the films on substrates was determined as 120 nm by Rutherford backscattering spectroscopy (RBS). Specular ultra-violet visible (UV-vis) gives the direct transition optical band gaps (E sub(g)) for AZO as-deposited films are 2.60 and 3.35 eV while that of 600 [degrees]C annealed films are 3.00 and 3.60 eV. The E sub(g) calculated from diffuse reflectance spectroscopy (DRS) UV-vis are more diverse in ZnO- and AZO-Si than the ZnO- and AZO-glass samples, although in both sets the E sub(g) tend to converge after annealing 600 [degrees]C. The Raman spectra of samples show multiphonon processes of higher order from the AZO and substrates. It is found that residual stresses are related to E sub(2) Raman mode. |
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ISSN: | 0921-4526 |
DOI: | 10.1016/j.physb.2015.09.022 |