Cp2TiCl2‑Catalyzed Regioselective Hydrocarboxylation of Alkenes with CO2
Cp2TiCl2-catalyzed regioselective hydrocarboxylation of alkenes with CO2 to give carboxylic acids in high yields has been developed in the presence of i PrMgCl. The reaction proceeds with a wide range of alkenes under mild conditions. Styrene and its derivatives can transform to α-aryl carboxylic ac...
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| Veröffentlicht in: | Organic letters 2016-05, Vol.18 (9), p.2050-2053 |
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| container_issue | 9 |
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| container_title | Organic letters |
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| creator | Shao, Peng Wang, Sheng Chen, Chao Xi, Chanjuan |
| description | Cp2TiCl2-catalyzed regioselective hydrocarboxylation of alkenes with CO2 to give carboxylic acids in high yields has been developed in the presence of i PrMgCl. The reaction proceeds with a wide range of alkenes under mild conditions. Styrene and its derivatives can transform to α-aryl carboxylic acids, and aliphatic alkenes can transform to form alkanoic acids. |
| doi_str_mv | 10.1021/acs.orglett.6b00665 |
| format | Article |
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| identifier | ISSN: 1523-7060 |
| ispartof | Organic letters, 2016-05, Vol.18 (9), p.2050-2053 |
| issn | 1523-7060 1523-7052 |
| language | eng |
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| source | ACS Publications |
| title | Cp2TiCl2‑Catalyzed Regioselective Hydrocarboxylation of Alkenes with CO2 |
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