Cp2TiCl2‑Catalyzed Regioselective Hydrocarboxylation of Alkenes with CO2

Cp2TiCl2‑Catalyzed Regioselective Hydrocarboxylation of Alkenes with CO2

Cp2TiCl2-catalyzed regioselective hydrocarboxylation of alkenes with CO2 to give carboxylic acids in high yields has been developed in the presence of i PrMgCl. The reaction proceeds with a wide range of alkenes under mild conditions. Styrene and its derivatives can transform to α-aryl carboxylic ac...

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Veröffentlicht in:Organic letters 2016-05, Vol.18 (9), p.2050-2053
Hauptverfasser: Shao, Peng, Wang, Sheng, Chen, Chao, Xi, Chanjuan
Format: Artikel
Sprache:eng
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Zusammenfassung:Cp2TiCl2-catalyzed regioselective hydrocarboxylation of alkenes with CO2 to give carboxylic acids in high yields has been developed in the presence of i PrMgCl. The reaction proceeds with a wide range of alkenes under mild conditions. Styrene and its derivatives can transform to α-aryl carboxylic acids, and aliphatic alkenes can transform to form alkanoic acids.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.6b00665