High-Performance, Solution-Processed, Embedded Multiscale Metallic Transparent Conductors
High-performance multiscale metallic transparent conductors (TCs) are demonstrated by incorporating Ag nanowire (NW) networks into microscale Ag grid structures. Highly conductive Ag grids are fabricated via direct imprinting of an Ag ion ink using a reservoir-assisted mold. In this mold, a macrosca...
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Veröffentlicht in: | ACS applied materials & interfaces 2016-05, Vol.8 (17), p.10937-10945 |
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creator | Oh, Yong Suk Lee, Hyunwoo Choi, Dong Yun Lee, Sung-Uk Kim, Hojin Yoo, Seunghyup Park, Inkyu Sung, Hyung Jin |
description | High-performance multiscale metallic transparent conductors (TCs) are demonstrated by incorporating Ag nanowire (NW) networks into microscale Ag grid structures. Highly conductive Ag grids are fabricated via direct imprinting of an Ag ion ink using a reservoir-assisted mold. In this mold, a macroscale cavity, called the “reservoir”, is designed to connect to a grid-patterned cavity. The reservoir has a large cavity volume, which reduces unwanted residual layers within the grid spacings by introducing a thinner liquid film. The reservoir undergoes a large volume reduction during mold deformation, which improves ink filling within the grid-patterned cavity through deformation-induced ink injection. The multiscale metallic TCs show a sheet resistance (R s) of |
doi_str_mv | 10.1021/acsami.6b02333 |
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Highly conductive Ag grids are fabricated via direct imprinting of an Ag ion ink using a reservoir-assisted mold. In this mold, a macroscale cavity, called the “reservoir”, is designed to connect to a grid-patterned cavity. The reservoir has a large cavity volume, which reduces unwanted residual layers within the grid spacings by introducing a thinner liquid film. The reservoir undergoes a large volume reduction during mold deformation, which improves ink filling within the grid-patterned cavity through deformation-induced ink injection. The multiscale metallic TCs show a sheet resistance (R s) of <1.5 Ω/sq and a transmittance (T) of 86% at 550 nm, superior to the corresponding values of Ag NW networks (R s of 15.6 Ω/sq at a similar T). We estimate the R s–T performances of the Ag grids using geometrical calculations and demonstrate that their integration can enhance the opto-electrical properties of the Ag NW networks. Multiscale metallic TCs are successfully transferred and embedded into a transparent, flexible, and UV-curable polymer matrix. The embedded multiscale metallic TCs show reasonable electromechanical and chemical stability. The utility of these TCs is demonstrated by fabricating flexible organic solar cells.</description><identifier>ISSN: 1944-8244</identifier><identifier>EISSN: 1944-8252</identifier><identifier>DOI: 10.1021/acsami.6b02333</identifier><identifier>PMID: 27074908</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>ACS applied materials & interfaces, 2016-05, Vol.8 (17), p.10937-10945</ispartof><rights>Copyright © 2016 American Chemical Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a330t-e773abb06b9c0dd018a6c2c21225cc4ab39cf2555b9ebb1a9a1fe98e49407f0d3</citedby><cites>FETCH-LOGICAL-a330t-e773abb06b9c0dd018a6c2c21225cc4ab39cf2555b9ebb1a9a1fe98e49407f0d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acsami.6b02333$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acsami.6b02333$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>314,780,784,2765,27076,27924,27925,56738,56788</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27074908$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Oh, Yong Suk</creatorcontrib><creatorcontrib>Lee, Hyunwoo</creatorcontrib><creatorcontrib>Choi, Dong Yun</creatorcontrib><creatorcontrib>Lee, Sung-Uk</creatorcontrib><creatorcontrib>Kim, Hojin</creatorcontrib><creatorcontrib>Yoo, Seunghyup</creatorcontrib><creatorcontrib>Park, Inkyu</creatorcontrib><creatorcontrib>Sung, Hyung Jin</creatorcontrib><title>High-Performance, Solution-Processed, Embedded Multiscale Metallic Transparent Conductors</title><title>ACS applied materials & interfaces</title><addtitle>ACS Appl. Mater. Interfaces</addtitle><description>High-performance multiscale metallic transparent conductors (TCs) are demonstrated by incorporating Ag nanowire (NW) networks into microscale Ag grid structures. Highly conductive Ag grids are fabricated via direct imprinting of an Ag ion ink using a reservoir-assisted mold. In this mold, a macroscale cavity, called the “reservoir”, is designed to connect to a grid-patterned cavity. The reservoir has a large cavity volume, which reduces unwanted residual layers within the grid spacings by introducing a thinner liquid film. The reservoir undergoes a large volume reduction during mold deformation, which improves ink filling within the grid-patterned cavity through deformation-induced ink injection. The multiscale metallic TCs show a sheet resistance (R s) of <1.5 Ω/sq and a transmittance (T) of 86% at 550 nm, superior to the corresponding values of Ag NW networks (R s of 15.6 Ω/sq at a similar T). We estimate the R s–T performances of the Ag grids using geometrical calculations and demonstrate that their integration can enhance the opto-electrical properties of the Ag NW networks. Multiscale metallic TCs are successfully transferred and embedded into a transparent, flexible, and UV-curable polymer matrix. The embedded multiscale metallic TCs show reasonable electromechanical and chemical stability. The utility of these TCs is demonstrated by fabricating flexible organic solar cells.</description><issn>1944-8244</issn><issn>1944-8252</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kLtOw0AQRVcIREKgpUQuEYrDvvzYEkWBICUiEqGgsvYxBkdrb9i1C_4eI4d0VDPFuVczB6FrgmcEU3IvdZB1NUsVpoyxEzQmgvM4pwk9Pe6cj9BFCDuMU0Zxco5GNMMZFzgfo_dl9fEZb8CXztey0TCNXp3t2so18cY7DSGAmUaLWoExYKJ1Z9sqaGkhWkMrra10tPWyCXvpoWmjuWtMp1vnwyU6K6UNcHWYE_T2uNjOl_Hq5el5_rCKJWO4jSHLmFQKp0pobAwmuUw11ZRQmmjNpWJClzRJEiVAKSKFJCWIHLjgOCuxYRN0O_TuvfvqILRF3R8I1soGXBcKkuUZzpOcZD06G1DtXQgeymLvq1r674Lg4ldnMegsDjr7wM2hu1M1mCP-568H7gagDxY71_mmf_W_th9zLoDG</recordid><startdate>20160504</startdate><enddate>20160504</enddate><creator>Oh, Yong Suk</creator><creator>Lee, Hyunwoo</creator><creator>Choi, Dong Yun</creator><creator>Lee, Sung-Uk</creator><creator>Kim, Hojin</creator><creator>Yoo, Seunghyup</creator><creator>Park, Inkyu</creator><creator>Sung, Hyung Jin</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20160504</creationdate><title>High-Performance, Solution-Processed, Embedded Multiscale Metallic Transparent Conductors</title><author>Oh, Yong Suk ; Lee, Hyunwoo ; Choi, Dong Yun ; Lee, Sung-Uk ; Kim, Hojin ; Yoo, Seunghyup ; Park, Inkyu ; Sung, Hyung Jin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a330t-e773abb06b9c0dd018a6c2c21225cc4ab39cf2555b9ebb1a9a1fe98e49407f0d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Oh, Yong Suk</creatorcontrib><creatorcontrib>Lee, Hyunwoo</creatorcontrib><creatorcontrib>Choi, Dong Yun</creatorcontrib><creatorcontrib>Lee, Sung-Uk</creatorcontrib><creatorcontrib>Kim, Hojin</creatorcontrib><creatorcontrib>Yoo, Seunghyup</creatorcontrib><creatorcontrib>Park, Inkyu</creatorcontrib><creatorcontrib>Sung, Hyung Jin</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>ACS applied materials & interfaces</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Oh, Yong Suk</au><au>Lee, Hyunwoo</au><au>Choi, Dong Yun</au><au>Lee, Sung-Uk</au><au>Kim, Hojin</au><au>Yoo, Seunghyup</au><au>Park, Inkyu</au><au>Sung, Hyung Jin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High-Performance, Solution-Processed, Embedded Multiscale Metallic Transparent Conductors</atitle><jtitle>ACS applied materials & interfaces</jtitle><addtitle>ACS Appl. Mater. Interfaces</addtitle><date>2016-05-04</date><risdate>2016</risdate><volume>8</volume><issue>17</issue><spage>10937</spage><epage>10945</epage><pages>10937-10945</pages><issn>1944-8244</issn><eissn>1944-8252</eissn><abstract>High-performance multiscale metallic transparent conductors (TCs) are demonstrated by incorporating Ag nanowire (NW) networks into microscale Ag grid structures. Highly conductive Ag grids are fabricated via direct imprinting of an Ag ion ink using a reservoir-assisted mold. In this mold, a macroscale cavity, called the “reservoir”, is designed to connect to a grid-patterned cavity. The reservoir has a large cavity volume, which reduces unwanted residual layers within the grid spacings by introducing a thinner liquid film. The reservoir undergoes a large volume reduction during mold deformation, which improves ink filling within the grid-patterned cavity through deformation-induced ink injection. The multiscale metallic TCs show a sheet resistance (R s) of <1.5 Ω/sq and a transmittance (T) of 86% at 550 nm, superior to the corresponding values of Ag NW networks (R s of 15.6 Ω/sq at a similar T). We estimate the R s–T performances of the Ag grids using geometrical calculations and demonstrate that their integration can enhance the opto-electrical properties of the Ag NW networks. Multiscale metallic TCs are successfully transferred and embedded into a transparent, flexible, and UV-curable polymer matrix. The embedded multiscale metallic TCs show reasonable electromechanical and chemical stability. The utility of these TCs is demonstrated by fabricating flexible organic solar cells.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>27074908</pmid><doi>10.1021/acsami.6b02333</doi><tpages>9</tpages></addata></record> |
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