Signatures of molecular orbital structure in lateral electron momentum distributions from strong-field ionization

Strong-field ionization of aligned diatomic and polyatomic molecules such as O2, N2, C2H4, and others in circularly polarized laser fields is investigated theoretically. By calculating the emission-angle-resolved lateral width of the momentum distribution perpendicular to the polarization plane, we...

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Veröffentlicht in:Physical review letters 2015-03, Vol.114 (10), p.103004-103004, Article 103004
Hauptverfasser: Petersen, Ingo, Henkel, Jost, Lein, Manfred
Format: Artikel
Sprache:eng
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Zusammenfassung:Strong-field ionization of aligned diatomic and polyatomic molecules such as O2, N2, C2H4, and others in circularly polarized laser fields is investigated theoretically. By calculating the emission-angle-resolved lateral width of the momentum distribution perpendicular to the polarization plane, we show that nodal planes in molecular orbitals are directly imprinted on the angular dependence of the width. We demonstrate that orbital symmetries can be distinguished with the information obtained by observing the lateral width in addition to the angular distributions.
ISSN:0031-9007
1079-7114
DOI:10.1103/physrevlett.114.103004