Site-Selective Approach to β-Fluorination: Photocatalyzed Ring Opening of Cyclopropanols

To expand upon the recent pioneering reports of catalyzed sp3 CH fluorination methods, the next rational step is to focus on directing “radical‐based fluorination” more effectively. One potential solution entails selective CC bond activation as a prelude to selective fluorination. Herein, we repor...

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Veröffentlicht in:	Chemistry : a European journal 2015-05, Vol.21 (22), p.8060-8063
Hauptverfasser:	Bloom, Steven, Bume, Desta Doro, Pitts, Cody Ross, Lectka, Thomas
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Alcohols Bonding Carbonyls cyclopropanols CC activation Fluorination photochemistry radical ions Ring opening Versatility
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