Cross-coupling between Aryl- and Alkenyldimethylsilanes and Organic Halides Promoted by a Copper(I) Iodide/Sodium Hydride/Ethylene Glycol System

Cross-coupling between Aryl- and Alkenyldimethylsilanes and Organic Halides Promoted by a Copper(I) Iodide/Sodium Hydride/Ethylene Glycol System

A copper(I) iodide/sodium hydride/ethylene glycol system promoted reaction of aryl- and alkenyldimethylsilanes with C(sp3)–X electrophiles bearing a β-hydrogen produced the cross-coupling products at ambient temperature within a short period of time.

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Veröffentlicht in:Chemistry letters 2015-06, Vol.44 (6), p.809-811
Hauptverfasser: Takeda, Takeshi, Takeda, Yuichiro, Tsubouchi, Akira
Format: Artikel
Sprache:eng
Schlagworte:
Ambient temperature
Bearing
Cross coupling
Ethylene glycol
Halides
Iodides
Sodium hydrides
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Beschreibung
Zusammenfassung:A copper(I) iodide/sodium hydride/ethylene glycol system promoted reaction of aryl- and alkenyldimethylsilanes with C(sp3)–X electrophiles bearing a β-hydrogen produced the cross-coupling products at ambient temperature within a short period of time.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.150171