Role of the Amide Carbonyl Groups in the Nitrile Hydratase Active Site for Nitrile Coordination Using Co(III) Complex with N2S3-type Ligand

Role of the Amide Carbonyl Groups in the Nitrile Hydratase Active Site for Nitrile Coordination Using Co(III) Complex with N2S3-type Ligand

The role of the amide carbonyl oxygens in the nitrile hydratase (NHase) active site for the nitrile coordination to the metal center was studied using a distorted square-pyramidal N2S3-type Co(III) complex at room temperature in the presence of a folded-sheet mesoporous material (FSM) or sodium cati...

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Veröffentlicht in:Chemistry letters 2015-06, Vol.44 (6), p.761-763
Hauptverfasser: Yano, Takuma, Ikeda, Tomohiro, Shibayama, Tomonori, Inomata, Tomohiko, Funahashi, Yasuhiro, Ozawa, Tomohiro, Masuda, Hideki
Format: Artikel
Sprache:eng
Schlagworte:
Amides
Carbonyl groups
Carbonyls
Cations
Distortion
Ligands
Nitriles
Sodium
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Zusammenfassung:The role of the amide carbonyl oxygens in the nitrile hydratase (NHase) active site for the nitrile coordination to the metal center was studied using a distorted square-pyramidal N2S3-type Co(III) complex at room temperature in the presence of a folded-sheet mesoporous material (FSM) or sodium cation.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.150084