Polymerization of vinyl fluoride in ionic liquid and ionic solutions

Polymerization of vinyl fluoride in ionic liquid and ionic solutions

Poly(vinyl fluoride) films are extensively used as protective, easy-clean materials in the photovoltaic and aerospace industries. However, polymerization of vinyl fluoride (VF) monomer typically requires high pressures (>5000 psi) due to the low solubility of VF monomer in the aqueous polymerizat...

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Veröffentlicht in:Polymer (Guilford) 2016-01, Vol.82, p.295-304
Hauptverfasser: Mather, Brian D., Reinartz, Nicole M., Shiflett, Mark B.
Format: Artikel
Sprache:eng
Schlagworte:
Anions
Chain transfer
Conversion
Emulsion polymerization
Fluorination
Fluoropolymer
Fractal-like morphology
Ionic liquid
Ionic liquids
Monomers
poly(vinyl fluoride)
Polymerization
Radical polymerization
Salt solutions
Vapor–liquid equilibria
Vinyl fluoride
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Zusammenfassung:Poly(vinyl fluoride) films are extensively used as protective, easy-clean materials in the photovoltaic and aerospace industries. However, polymerization of vinyl fluoride (VF) monomer typically requires high pressures (>5000 psi) due to the low solubility of VF monomer in the aqueous polymerization medium. VF was found to exhibit high solubilities in fluorinated ionic liquids and concentrated aqueous ionic salt solutions at low pressures (
ISSN:0032-3861
1873-2291
DOI:10.1016/j.polymer.2015.11.012