Carbohydrates as enantioinduction components in stereoselective catalysis

Carbohydrate derivatives are readily available chiral molecules, yet they are infrequently employed as enantioinduction components in stereoselective catalysis. In this review, synthetic approaches to carbohydrate-based ligands and catalysts are outlined, along with example applications in enantiose...

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Veröffentlicht in:Organic & biomolecular chemistry 2016-01, Vol.14 (17), p.48-417
Hauptverfasser: Henderson, Alexander S, Bower, John F, Galan, M. Carmen
Format: Artikel
Sprache:eng
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Zusammenfassung:Carbohydrate derivatives are readily available chiral molecules, yet they are infrequently employed as enantioinduction components in stereoselective catalysis. In this review, synthetic approaches to carbohydrate-based ligands and catalysts are outlined, along with example applications in enantioselective catalysis. A wide range of carbohydrate-based functionality is covered, and key trends and future opportunities are identified. In this review, synthetic approaches to carbohydrate-based ligands and catalysts are outlined, along with example applications in enantioselective catalysis.
ISSN:1477-0520
1477-0539
DOI:10.1039/c6ob00368k